Mononuclear Zn(II)- and Cu(II)-complexes of a hydroxynaphthalene-derived dipicolylamine: fluorescent sensing behaviours toward pyrophosphate ions
SCIE
SCOPUS
- Title
- Mononuclear Zn(II)- and Cu(II)-complexes of a hydroxynaphthalene-derived dipicolylamine: fluorescent sensing behaviours toward pyrophosphate ions
- Authors
- Roy, B; Rao, AS; Ahn, KH
- Date Issued
- 2011-01
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- Mononuclear Zn(II)-DPA and Cu(II)-DPA complexes crafted on 2-hydroxy-6-cyanonaphthalene fluorophore selectively recognize PPi over ATP and other anions including inorganic phosphates in aqueous medium, showing turn-on type fluorescence enhancements. Coordination of a hydroxyl group of the fluorophore, directly or in alkoxy form, to the central metal ion is crucial for the sensing processes. Both the complexes elicit a fluorescence increase in a time-dependent fashion.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/11877
- DOI
- 10.1039/C1OB05999H
- ISSN
- 1477-0520
- Article Type
- Article
- Citation
- ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 9, no. 22, page. 7774 - 7779, 2011-01
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