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Growth of hafnium aluminate thin films by direct liquid injection metallorganic CVD using Hf[N(C2H5)(2)](4) and Al((OC3H7)-C-i)(3) SCIE SCOPUS

Title
Growth of hafnium aluminate thin films by direct liquid injection metallorganic CVD using Hf[N(C2H5)(2)](4) and Al((OC3H7)-C-i)(3)
Authors
Song, MKKang, SWRhee, SW
Date Issued
2005-01
Publisher
ELECTROCHEMICAL SOC INC
Abstract
A mixtured solution of Hf[N(C2H5)(2)](4) (tetrakis-diethylamido-hafnium, TDEAH) and Al((OC3H7)-C-i)(3) (aluminum iso-propoxide) dissolved in n-octane was used in the direct liquid injection metallorganic chemical vapor deposition (DLI-MOCVD) for the deposit ion of hafnium aluminate (HfAlxOy) thin films. The effect of the deposition temperature and the concentration of the precursors in the solution on the deposition rate and the composition of the hafnium aluminate film were studied in the deposition temperature range of 200-475degreesC. The deposition rate was increased up to the deposition temperature of 350degreesC with the activation energy of about 3.6 kcal/mol and then decreased due to the gas-phase dissociation of the precursor. The incorporation of aluminum into the film depends almost linearly on the concentration of the aluminum precursor in the solution. As the At incorporation in the film was increased, crystallization temperature of the film was increased, but the grain size measured by scanning electron microscope was not significantly changed with the increase of the annealing temperature. For 100 nm thin film, the dielectric constant and the leakage current density of Hf aluminate film (about 65% aluminum phase) annealed at 800degreesC was 11.1 and 2.3 x 10(-7) A/cm(2) at 5 V, respectively. (C) 2005 The Electrochemical Society. All rights reserved.
URI
https://oasis.postech.ac.kr/handle/2014.oak/11146
DOI
10.1149/1.1851058
ISSN
0013-4651
Article Type
Article
Citation
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, vol. 152, no. 2, page. C108 - C112, 2005-01
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