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Cited 21 time in webofscience Cited 26 time in scopus
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dc.contributor.authorOh, SJ-
dc.contributor.authorYoon, CW-
dc.contributor.authorPark, JW-
dc.date.accessioned2015-06-25T02:29:30Z-
dc.date.available2015-06-25T02:29:30Z-
dc.date.created2009-03-16-
dc.date.issued1996-03-
dc.identifier.issn0300-9580-
dc.identifier.other2015-OAK-0000009352en_US
dc.identifier.urihttps://oasis.postech.ac.kr/handle/2014.oak/11063-
dc.description.abstractLanthanide(III) cryptate (2.2.1) chlorides [Ln(2.2.1)Cl-3; Ln = La, Ce, Eu] are effective in catalysing the hydrolysis of 4-nitrophenyl diphenyl phosphate. Kinetic studies reveal that the europium(III) (2.2.1) chloride catalyses the hydrolysis efficiently (k 1.8 x 10(-2) s(-1) at 1.6 mmol dm(-3), turnover number = 12 at pH 9.00 and 25 degrees C). The reactivity of the cerium(III) complex is enhanced by the presence of molecular oxygen, Analysis of the products of the hydrolysis shows that the selectivity toward yielding 4-nitrophenol against phenol is unusually high (ratio = 17:1).-
dc.description.statementofresponsibilityopenen_US
dc.languageEnglish-
dc.publisherROYAL SOC CHEMISTRY-
dc.relation.isPartOfJOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2-
dc.rightsBY_NC_NDen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/2.0/kren_US
dc.titleCatalytic hydrolysis of phosphate triesters by lanthanide(III) cryptate (2.2.1) complexes-
dc.typeArticle-
dc.contributor.college화학과en_US
dc.identifier.doi10.1039/p29960000329-
dc.author.googleOh, SJen_US
dc.author.googleYoon, CWen_US
dc.author.googlePark, JWen_US
dc.relation.issue3en_US
dc.relation.startpage329en_US
dc.relation.lastpage331en_US
dc.contributor.id10053210en_US
dc.relation.journalJOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2en_US
dc.relation.indexSCI급, SCOPUS 등재논문en_US
dc.relation.sciSCIen_US
dc.collections.nameJournal Papersen_US
dc.type.rimsART-
dc.identifier.bibliographicCitationJOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no.3, pp.329 - 331-
dc.identifier.wosidA1996TZ02000009-
dc.date.tcdate2019-01-01-
dc.citation.endPage331-
dc.citation.number3-
dc.citation.startPage329-
dc.citation.titleJOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2-
dc.contributor.affiliatedAuthorPark, JW-
dc.identifier.scopusid2-s2.0-0000936083-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.wostc18-
dc.type.docTypeArticle-
dc.subject.keywordPlusMETALLOMICELLES-
dc.subject.keywordPlusCLEAVAGE-
dc.subject.keywordPlusESTERS-
dc.subject.keywordPlusACID-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-

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