DC Field | Value | Language |
---|---|---|
dc.contributor.author | Oh, SJ | - |
dc.contributor.author | Yoon, CW | - |
dc.contributor.author | Park, JW | - |
dc.date.accessioned | 2015-06-25T02:29:30Z | - |
dc.date.available | 2015-06-25T02:29:30Z | - |
dc.date.created | 2009-03-16 | - |
dc.date.issued | 1996-03 | - |
dc.identifier.issn | 0300-9580 | - |
dc.identifier.other | 2015-OAK-0000009352 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/11063 | - |
dc.description.abstract | Lanthanide(III) cryptate (2.2.1) chlorides [Ln(2.2.1)Cl-3; Ln = La, Ce, Eu] are effective in catalysing the hydrolysis of 4-nitrophenyl diphenyl phosphate. Kinetic studies reveal that the europium(III) (2.2.1) chloride catalyses the hydrolysis efficiently (k 1.8 x 10(-2) s(-1) at 1.6 mmol dm(-3), turnover number = 12 at pH 9.00 and 25 degrees C). The reactivity of the cerium(III) complex is enhanced by the presence of molecular oxygen, Analysis of the products of the hydrolysis shows that the selectivity toward yielding 4-nitrophenol against phenol is unusually high (ratio = 17:1). | - |
dc.description.statementofresponsibility | open | en_US |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | - |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | Catalytic hydrolysis of phosphate triesters by lanthanide(III) cryptate (2.2.1) complexes | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | en_US |
dc.identifier.doi | 10.1039/p29960000329 | - |
dc.author.google | Oh, SJ | en_US |
dc.author.google | Yoon, CW | en_US |
dc.author.google | Park, JW | en_US |
dc.relation.issue | 3 | en_US |
dc.relation.startpage | 329 | en_US |
dc.relation.lastpage | 331 | en_US |
dc.contributor.id | 10053210 | en_US |
dc.relation.journal | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | en_US |
dc.relation.index | SCI급, SCOPUS 등재논문 | en_US |
dc.relation.sci | SCI | en_US |
dc.collections.name | Journal Papers | en_US |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, no.3, pp.329 - 331 | - |
dc.identifier.wosid | A1996TZ02000009 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 331 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 329 | - |
dc.citation.title | JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | - |
dc.contributor.affiliatedAuthor | Park, JW | - |
dc.identifier.scopusid | 2-s2.0-0000936083 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 18 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | METALLOMICELLES | - |
dc.subject.keywordPlus | CLEAVAGE | - |
dc.subject.keywordPlus | ESTERS | - |
dc.subject.keywordPlus | ACID | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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