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Copper-Catalyzed Diastereoselective and Enantioselective Addition of 1,1-Diborylalkanes to Cyclic Ketimines and alpha-Imino Esters

Title
Copper-Catalyzed Diastereoselective and Enantioselective Addition of 1,1-Diborylalkanes to Cyclic Ketimines and alpha-Imino Esters
Authors
CHO, SEUNG HWANJUNG, HO KIMSHIN, MINKYEONG
Date Issued
Aug-2019
Publisher
AMER CHEMICAL SOC
Abstract
We report broadly applicable copper catalytic conditions for the diastereoselective and enantioselective 1,2-addition of 1,1-diborylalkanes to cyclic ketimines and alpha-imino esters. The developed method provides various beta-aminoboronate esters bearing adjacent stereocenters with high diastereo- and enantioselectivity. Synthetic applications for converting the obtained beta-aminoboronate esters to a diverse array of synthetically useful chiral compounds are demonstrated.
URI
http://oasis.postech.ac.kr/handle/2014.oak/99696
ISSN
2155-5435
Article Type
Article
Citation
ACS CATALYSIS, vol. 9, no. 9, page. 8503 - 8508, 2019-08
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 CHO, SEUNG HWAN
Dept of Chemistry
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