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Synthesis and Characterization of Diketopyrrolopyrrole-Based Conjugated Polymers with Bithiophene and Biselenophene for Organic Thin Film Transistors

Title
Synthesis and Characterization of Diketopyrrolopyrrole-Based Conjugated Polymers with Bithiophene and Biselenophene for Organic Thin Film Transistors
Authors
Hee Su KimEul-Yong ShinGyujin ParkNOH, YONG YOUNGDo-Hoon Hwang
Date Issued
Oct-2019
Publisher
AMER SCIENTIFIC PUBLISHERS
Abstract
In this study, two new thieno[3,2-b] thiophene-diketopyrrolopyrrole (DPP)-based polymers, poly{2,5-bis(2-dodecylhexadecyl)-3,6-bis(thieno[3,2-b] thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-alt-2,2'-bithiophene} (PTTDPP-BT) and {2,5-bis(2-dodecylhexadecyl)-3,6-bis(thieno[3,2-b] thiophen-2-yl) pyrrolo[3,4-c] pyrrole-1,4(2H, 5H)-dione-alt-2,2'-selenophene} (PTTDPP-BSe), which contained bithiophene (BT) and biselenophene (BSe) units, respectively, were designed and synthesized. The introduction of BT and BSe units affected the optical, electrochemical, morphological, and charge transport properties of the polymers. Experimental results revealed that the frontier molecular orbital energy levels of PTTDPP-BT were slightly higher because of the relatively strong electron donating ability of the sulfur atom and the polymer also exhibited good solubility. The maximum mobility in the case of PTTDPP-BT at 250 degrees C was 0.068 cm(2) V-1 s(-1) and that of PTTDPP-BSe was 0.029 cm(2) V-1 s(-1) (at 200 degrees C).
Keywords
HOLE MOBILITY; ELECTRON
URI
http://oasis.postech.ac.kr/handle/2014.oak/98995
ISSN
1533-4880
Article Type
Article
Citation
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, vol. 19, no. 10, page. 6158 - 6163, 2019-10
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 NOH, YONG YOUNG
Dept. of Chemical Enginrg
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