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Recyclable gold nanoparticle catalyst for the aerobic alcohol oxidation and C-C bond forming reaction between primary alcohols and ketones under ambient conditions

Title
Recyclable gold nanoparticle catalyst for the aerobic alcohol oxidation and C-C bond forming reaction between primary alcohols and ketones under ambient conditions
Authors
Kim, SBae, SWLee, JSPark, J
POSTECH Authors
Park, J
Date Issued
Feb-2009
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Abstract
A recyclable gold catalyst is synthesized from readily available reagents by immobilizing gold nanoparticles in aluminum oxyhydroxide support through a simple sol-gel method. The catalyst showed the high activity even at room temperature in the aerobic oxidation of various alcohols and in the coupling reaction between primary alcohols and ketones. (C) 2008 Elsevier Ltd. All rights reserved.
Keywords
Heterogeneous catalyst; Gold nanoparticle; Aerobic alcohol oxidation; Room temperature; C-C bond formation; DIRECT ALPHA-ALKYLATION; SOLVENT-FREE OXIDATION; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; HETEROGENEOUS CATALYST; ROOM-TEMPERATURE; HYDROGENATION; ALDEHYDES; HYDROXYAPATITE; NANOCLUSTERS
URI
http://oasis.postech.ac.kr/handle/2014.oak/26286
DOI
10.1016/J.TET.2008.1
ISSN
0040-4020
Article Type
Article
Citation
TETRAHEDRON, vol. 65, no. 7, page. 1461 - 1466, 2009-02
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 PARK, JAIWOOK
Dept of Chemistry
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