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Magnetically separable Pd catalyst for highly selective epoxide hydrogenolysis under mild conditions

Title
Magnetically separable Pd catalyst for highly selective epoxide hydrogenolysis under mild conditions
Authors
Kwon, MSPark, ISJang, JSLee, JSPark, J박재욱
Date Issued
Aug-2007
Publisher
AMER CHEMICAL SOC
Abstract
A magnetically separable palladium catalyst was synthesized simply through a sol-gel process incorporating palladium nanoparticles and superparamagnetic iron oxide nanoparticles in aluminum oxyhydroxide matrix, which is highly active and selective for epoxide hydrogenolysis at room temperature under 1 atm H-2. The catalyst was recycled for 25 times without loss of the activity.
Keywords
AEROBIC ALCOHOL OXIDATION; CROSS-COUPLING REACTIONS; PALLADIUM NANOPARTICLES; ALKENE HYDROGENATION; ALPHA-ALKYLATION; POLYMERS; KETONES; SILICA
URI
http://oasis.postech.ac.kr/handle/2014.oak/23236
DOI
10.1021/OL701456W
ISSN
1523-7060
Article Type
ARTICLE
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